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Universidad de la Costa, CUC. Calle 58 # 55 - 66. Barranquilla, Colombia. 336 22 00. repositorioredicuc@cuc.edu.co. Corporación Universidad de la Costa.

A Fragmentation Mechanism Of Homemade Explosive TMDD Using DART-MS And Isotopic Labeling

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A Fragmentation Mechanism Of Homemade (230.5Kb)
Date
2018-02-01
Author
Zarate Pedroza, Alexander
Colpas Castillo, Fredy
Alcázar Franco, Daniel Jesús
Cabrera Lafaurie, Wilman Alfonso
Espinosa Fuentes, Eduardo Antonio
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URI: http://hdl.handle.net/11323/1677

Abstract

A fragmentation mechanism and characterization for the first time using Direct Analysis in Real Time-Time of Flight-Mass Spectrometry (DART-TOF-MS) of the tetramethylene diperoxide dicarbamide (TMDD) compound were presented. The MS-spectrum may support other research about devices and detection in real scene. The mass spectrum of TMDD obtained using DART ionization in the positive-ion detection mode exhibited a strong peak at m/z 254 representing an ammonium adduct ([TMMD·NH4]+). There was another peak at m/z 237, which represented the protonated molecule ([TMDD·H]+) of TMDD. These two peaks corroborated the identity of the analyte. The DART-MS spectra of the TMDD-isotopomer successfully corroborated the respective molecular tails. The principal fragmentation residues also showed coherence according to the number of isotopically labeled atoms on the TMDD structure. In contrast with other organic peroxides analyzed by this technique, TMDD exhibited substantial fragmentation. The theoretical modeling results showed that the fragmentation mechanism of the TMDD ion adduct is strongly dependent of the TMDD ring flexibility and the hydrogen bonding formed between the nitrogen and oxygen atoms and the atmospheric proton.
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Universidad de la Costa, CUC

  • Calle 58 # 55 - 66. Barranquilla, Colombia

  • 336 22 00

  • repositorioredicuc@cuc.edu.co

Corporación Universidad de la Costa CUC, Personería Jurídica con Resolución No. 352 del 23 de abril de 1971 y reconocida como Universidad mediante resolución 3235 del 28 de marzo de 2012 expedida por el MEN. Institución de Educación Superior sujeta a inspección y vigilancia por el Ministerio de Educación Nacional.

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  • Recuperador Primo

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