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dc.creatorAlcázar Franco, Daniel Jesús
dc.date.accessioned2018-11-22T15:02:50Z
dc.date.available2018-11-22T15:02:50Z
dc.date.issued2013
dc.identifier.issn1532-2432
dc.identifier.urihttp://hdl.handle.net/11323/1710
dc.description.abstractA series of 2,2′-(dihydropyrimidine-1,3(2H,4H)-diyldimethanediyl)bis(substituted-phenols) was synthesized using a Mannich-type reaction between the macrocyclic aminal 1,3,7,9,13,15,19,21- ctaazapentacyclo[19.3.1.13,7.19,13.115,19]octacosane (OAPO) (1) and substituted phenols in basic media. These previously unreported compounds were separated from the reaction mixture by column chromatography in highly pure form with 25–75% yields. The most stable conformer was predicted using AM1-type semiempirical quantum chemical calculationsspa
dc.language.isoengeng
dc.publisherUniversidad de la Costa CUCeng
dc.subjectAnomeric effecteng
dc.subjectHexahydropyrimidineeng
dc.subjectMannich baseseng
dc.subjectOrtho-regioselectivityeng
dc.titleSimple One-Pot Synthesis of New Derivatives of the Macrocyclic Aminal 1,3,7,9,13,15,19,21-octaazapentacyclo-[19.3.1.13,7.19,13.115,19]octacosane (OAPO)eng
dc.typeArticleeng


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