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dc.contributor.authorde O. Salomón, Yamil
dc.contributor.authorgeorgin, jordanaspa
dc.contributor.authorReis, Glaydsonspa
dc.contributor.authorLima, Éder Claudiospa
dc.contributor.authorS. Oliveira, Marcos Lspa
dc.contributor.authorFranco, Disonspa
dc.contributor.authorSchadeck Netto, Matiasspa
dc.contributor.authorAllasia, Danielspa
dc.contributor.authorDotto, Guilherme Luizspa
dc.description.abstractWastes from the Pacara Earpod tree (Enterolobium contortisilquum) and Ironwood (Caesalpinia leiostachya) seeds were studied as biosorbents for the removal of basic fuchsin from waters. Both biosorbents were prepared and characterized by different analytical methods. The characterization data showed that both materials were mainly composed of lignin, cellulose, and hemicellulose. Both biosorbents exhibited roughened surfaces and surface functional groups such as C-H, C=O, C=C, C-O, C-N, and OH bonds. Furthermore, the XRD pattern shows an amorphous phase with a wide peak from 10 to 30° due to the lignin. In terms of dosage and pH, the use of 1 g L−1 and 9.0, respectively, is recommended. The initial concentrations for the biosorption kinetics ranged from 50 to 500 mg L−1, where the Pacara ear and the Ironwood reached an adsorption capacity of 145.62 and 100.743 mg g−1 for the 500 mg L−1. The pseudo-second-order was found to be the proper model for describing biosorption of basic fuchsin onto Pacara Earpod tree and Ironwood, respectively. For the isotherm experiments, the maximum experimental biosorption capacity was found to be 166.858 and 110.317 mg g−1 for the Pacara Earpod and Ironwood for the initial concentration of 500 mg L−1 at 328 K. The Langmuir and the Tóth models were the best for representing the equilibrium curves for the basic fuchsin on the Pacara Earpod and the Ironwood, respectively. Maximum adsorption capacities of 177.084 mg g−1 and 136.526 mg g−1 were achieved for the Pacara Earpod tree and Ironwood, respectively. The biosorption process was spontaneous, endothermic, and favorable for both biosorbents. The biosorbents were also applied for coloration removal of simulated textile effluents, reaching 66% and 54% for the Pacara Earpod and Ironwood, respectively. For the final application, the materials were used in fixed-bed biosorption, with an initial concentration of 200 mg L−1, reaching breakthrough times of 710 and 415 min, leading to biosorption capacities of the column of 124.5 and 76.5 mg g−1, for the Pacara Earpod and Ironwood,
dc.publisherCorporación Universidad de la Costaspa
dc.rightsCC0 1.0 Universalspa
dc.sourceEnvironmental Science and Pollution Researchspa
dc.subjectPacara earpod tree seedsspa
dc.subjectBasic fuchsin from the watersspa
dc.titleUtilization of Pacara Earpod tree (Enterolobium contortisilquum) and Ironwood (Caesalpinia leiostachya) seeds as low-cost biosorbents for removal of basic fuchsinspa
dc.identifier.instnameCorporación Universidad de la Costaspa
dc.identifier.reponameREDICUC - Repositorio CUCspa
dc.relation.referencesAksu Z, Tatli AI, Tunç Ö (2008) A comparative adsorption/biosorption study of Acid Blue 161: effect of temperature on equilibrium and kinetic parameters. Chem Eng J 142:23–39spa
dc.relation.referencesArchin S, Sharifi SH, Asadpour G (2019) Optimization and modeling of simultaneous ultrasound-assisted adsorption of binary dyes using activated carbon from tobacco residues: response surface methodology. J Clean Prod:239spa
dc.relation.referencesBabalola JO, Koiki BA, Eniayewu Y, Salimonu A, Olowoyo JO, Oninla VO, Omorogie MO (2016a) Adsorption efficacy of Cedrela odorata seed waste for dyes: non-linear fractal kinetics and non-linear equilibrium studies. J Environ Chem Eng 4:3527–3536spa
dc.relation.referencesBabalola JO, Olowoyo JO, Durojaiye AO, Olatunde AM, Unuabonah EI, Omorogie MO (2016b) Understanding the removal and regeneration potentials of biogenic wastes for toxic metals and organic dyes. J Taiwan Inst Chem Eng 58:490–499spa
dc.relation.referencesBabalola JO, Bamidele TM, Adeniji EA, Odozi NW, Olatunde AM, Omorogie MO (2016c) Adsorptive modelling of toxic cations and ionic dyes onto cellulosic extract. Model Earth Syst Environ 2:1–15spa
dc.relation.referencesBabalola JO, Olayiwola FT, Olowoyo JO, Alabi AH, Unuabonah EI, Ofomaja AE, Omorogie MO (2017) Adsorption and desorption kinetics of toxic organic and inorganic ions using an indigenous biomass: Terminalia ivorensis seed waste. Int J Ind Chem 8:207–220spa
dc.relation.referencesBohart GS, Adams EQ (1920) Some aspects of the behavior of charcoal with respect to chlorine. J Amer Chem Soc 42:523–544spa
dc.relation.referencesCarvalho CDO, Costa Rodrigues DL, Lima EC, Umpierres CS, Caicedo Chaguez DF, Machado FM (2019) Kinetic, equilibrium, and, thermodynamic studies on the adsorption of ciprofloxacin by activated carbon produced from Jeriva (Syagrus romanzoffiana). Environ Sci Pollut Res 26:4690–4702spa
dc.relation.referencesDa Silva DCC, Pietrobelli JMTDA (2019) Residual biomass of chia seeds (Salvia hispanica) oil extraction as low cost and eco-friendly biosorbent for effective reactive yellow B2R textile dye removal: characterization, kinetic, thermodynamic and isotherm studies. J Environ Chem Eng 7:103008spa
dc.relation.referencesDe Oliveira AVB, Rizzato TM, Barros BCB et al (2019) Physicochemical modifications of sugarcane and cassava agro-industrial wastes for applications as biosorbents. Bioresour Technol Reports 7:100294spa
dc.relation.referencesDhodapkar R, Rao NN, Pande SP, Nandy T, Devotta S (2007) Adsorption of cationic dyes on Jalshakti®, super absorbent polymer and photocatalytic regeneration of the adsorbent. React Funct Polym 67:540–548spa
dc.relation.referencesdos Reis GS, Thue PS, Cazacliu BG, Lima EC, Sampaio CH, Quattrone M, Ovsyannikova E, Kruse A, Dotto GL (2020a) Effect of concrete carbonation on phosphate removal through adsorption process and its potential application as fertilizer. J Clean Prod 256:120416spa
dc.relation.referencesdos Reis GS, Cazacliu BG, Correa CR, Ovsyannikova E, Kruse A, Sampaio CH, Lima EC, Dotto GL (2020b) Adsorption and recovery of phosphate from aqueous solution by the construction and demolition wastes sludge and its potential use as phosphate-based fertilizer. J Environ Chem Eng 8:103605spa
dc.relation.referencesDotto GL, McKay G (2020) Current scenario and challenges in adsorption for water treatment. J Environ Chem Eng 8:103988spa
dc.relation.referencesEl Haddad M (2016) Removal of basic fuchsin dye from water using mussel shell biomass waste as an adsorbent: equilibrium, kinetics, and thermodynamics. J Taibah Univ Sci 10:664–674spa
dc.relation.referencesElovich SY, Larinov OG (1962) Theory of adsorption from solutions of non-electrolytes on solid (I) equation adsorption from solutions and the analysis of its simplest form, (II) verification of the equation of adsorption isotherm from solutions. Izv Akad Nauk SSSR Otd Khim 2:209spa
dc.relation.referencesFranco DSP, Georgin J, Drumm FC, Netto MS, Allasia D, Oliveira MLS, Dotto GL (2020) Araticum (Annona crassiflora) seed powder (ASP) for the treatment of colored effluents by biosorption. Environ Sci Pollut Res 27:11184–11194spa
dc.relation.referencesFreundlich HMF (1906) Over the adsorption in solution. J Phys Chem 57:385–471spa
dc.relation.referencesGeorgin J, Drumm FC, Grassi P, Franco D, Allasia D, Dotto GL (2018) Potential of Araucaria angustifolia bark as adsorbent to remove gentian violet dye from aqueous effluents. Water Sci Technol 78:1693–1703spa
dc.relation.referencesGeorgin J, Franco DSP, Grassi P, Tonato D, Piccilli DGA, Meili L, Dotto GL (2019) Potential of Cedrela fissilis bark as an adsorbent for the removal of red 97 dye from aqueous effluents. Environ Sci Pollut Res 26:19207–19219spa
dc.relation.referencesGeorgin J, Franco D, Drumm FC, Grassi P, Netto MS, Allasia D, Dotto GL (2020) Powdered biosorbent from the mandacaru cactus (Cereus jamacaru) for discontinuous and continuous removal of basic fuchsin from aqueous solutions. Powder Technol 364:584–592spa
dc.relation.referencesGuan Y, Wang S, Wang X, Sun C, Wang Y, Hu L (2018) Preparation of mesoporous Al-MCM-41 from natural palygorskite and its adsorption performance for hazardous aniline dye-basic fuchsin. Micro Meso Mater 265:266–274spa
dc.relation.referencesGupta VK, Mittal A, Gajbe V, Mittal J (2008) Adsorption of basic fuchsin using waste materials-bottom ash and deoiled soya-as adsorbents. J Colloid Interface Sci 319:30–39spa
dc.relation.referencesHan Q, Wang J, Goodman BA, Xie J, Liu Z (2020) High adsorption of methylene blue by activated carbon prepared from phosphoric acid treated eucalyptus residue. Powder Technol 366:239–248spa
dc.relation.referencesHernandes PT, Oliveira MLS, Georgin J, Franco DSP, Allasia D, Dotto GL (2019) Adsorptive decontamination of wastewater containing methylene blue dye using golden trumpet tree bark (Handroanthus albus). Environ Sci Pollut Res 26:31924–31933spa
dc.relation.referencesHo YS, McKay G (1998) Pseudo-second order model for sorption processes. Process Biochem 34:451–465spa
dc.relation.referencesHuang LH, Kong JJ, Wang WL, Zhang CL, Niu SF, Gao BY (2012) Study on Fe(III) and Mn(II) modified activated carbons derived from Zizania latifolia to removal basic fuchsin. Desalination 286:268–276spa
dc.relation.referencesJain SN, Gogate PR (2017) Adsorptive removal of acid violet 17 dye from wastewater using biosorbent obtained from NaOH and H2SO4 activation of fallen leaves of Ficus racemosa. J Mol Liq 243:132–143spa
dc.relation.referencesJain SN, Tamboli SR, Sutar DS, Jadhav SR, Marathe JV, Shaikh AA, Prajapati AA (2020) Batch and continuous studies for adsorption of anionic dye onto waste tea residue: kinetic, equilibrium, breakthrough and reusability studies. J Clean Prod 252:119778spa
dc.relation.referencesKalita S, Pathak M, Devi G, Sarma HP, Bhattacharyya KG, Sarma A, Devi A (2017) Utilization of Euryale ferox Salisbury seed shell for removal of basic fuchsin dye from water: equilibrium and kinetics investigation. RSC Adv 7:27248–27259spa
dc.relation.referencesKasperiski FM, Lima EC, Reis GS, Da Costa JB, Dotto GL, Dias SLP, Cunha MR, Pavan F, Correa CS (2018) Preparation of CTAB-functionalized Aqai Stalk and its efficient application as adsorbent for the removal of Direct Blue 15 and Direct Red 23 dyes from aqueous media. Chem Eng Commun 205:1520–1536spa
dc.relation.referencesKhan TA, Khan EA, Shahjahan (2015) Removal of basic dyes from aqueous solution by adsorption onto binary iron-manganese oxide coated kaolinite: non-linear isotherm and kinetics modeling. Appl Clay Sci 107:70–77spa
dc.relation.referencesLagergren S (1898) (1898) About the theory of so-called adsorption of soluble substances. Kung Svenska Vetenskap 4:1–39spa
dc.relation.referencesLangmuir I (1918) The adsorption of gases on plane surfaces of glass, mica and platinum. J Am Chem Soc 40:1361–1403spa
dc.relation.referencesLeite AJB, Lima EC, dos Reis GS, Thue PS, Saucier C, Rodembusch FS, Dias SLP, Umpierres CS, Dotto GL (2017) Hybrid adsorbents of tannin and APTES (3-aminopropyltriethoxysilane) and their application for the highly efficient removal of acid red 1 dye from aqueous solutions. J Environ Chem Eng 5:4307–4318spa
dc.relation.referencesLi Z, Sellaoui L, Dotto GL, Lamine AB, Bonilla-Petriciolet A, Hanafy H, Belmabrouk H, Netto MS, Erto A (2019) Interpretation of the adsorption mechanism of Reactive Black 5 and Ponceau 4R dyes on chitosan/polyamide nanofibers via advanced statistical physics model. J Mol Liq 285:165–170spa
dc.relation.referencesLima EC, Hosseini-Bandegharaei A, Moreno-Piraján JC, Anastopoulos I (2019) A critical review of the estimation of the thermodynamic parameters on adsorption equilibria. Wrong use of equilibrium constant in the Van’t Hoof equation for calculation of thermodynamic parameters of adsorption. J Mol Liq 273:425–434spa
dc.relation.referencesLiu Y, Shen L (2008) A general rate law equation for biosorption. Biochem Eng J 38:390–394spa
dc.relation.referencesLorenzi H (2013) Brazilian trees: identification and cultivation manual for native Brazilian trees l, vol. 2- 4. Ed. -Nova Odessa, SP: Inst. Plantarum,
dc.relation.referencesMadan S, Shaw R, Tiwari S, Tiwari SK (2019) Adsorption dynamics of Congo red dye removal using ZnO functionalized high silica zeolitic particles. Appl Surf Sci 487:907–917spa
dc.relation.referencesNguyen CH, Juang RS (2019) Efficient removal of methylene blue dye by a hybrid adsorption-photocatalysis process using reduced graphene oxide/titanate nanotube composites for water reuse. J Ind Eng Chem 76:296–309spa
dc.relation.referencesNowrouzi M, Younesi H, Bahramifar N (2017) High efficient carbon dioxide capture onto as-synthesized activated carbon by chemical activation of Persian Ironwood biomass and the economic pre-feasibility study for scale-up. J Clean Prod 168:499–509spa
dc.relation.referencesNwodika C, Onukwuli OD (2017) Adsorption study of kinetics and equilibrium of basic dye on kola nut pod carbon. Gazi Univ J Sci 30:86–102spa
dc.relation.referencesOyelude EO, Frimpong F, Dawson D (2015) Studies on the removal of basic fuchsin dye from aqueous solution by HCl treated malted sorghum mash. J Mater Environ Sci 6:1126–1136spa
dc.relation.referencesPang X, Sellaoui L, Franco D, Dotto GL, Georgin J, Bajahzar A, Belmabrouk H, Ben Lamine A, Bonilla-Petriciolet A, Li Z (2019) Adsorption of crystal violet on biomasses from pecan nutshell, para chestnut husk, araucaria bark and palm cactus: experimental study and theoretical modeling via monolayer and double layer statistical physics models. Chem Eng J 378:122101spa
dc.relation.referencesPutri KNA, Keereerak A, Chinpa W (2020) Novel cellulose-based biosorbent from lemongrass leaf combined with cellulose acetate for adsorption of crystal violet. Int J Biol Macromol 156:762–772spa
dc.relation.referencesScheufele FB, Staudt J, Ueda MH, Ribeiro C, Steffen V, Borba CE, Módenes AN, Kroumov AD (2020) Biosorption of direct black dye by cassava root husks: kinetics, equilibrium, thermodynamics and mechanism assessment. J Environ Chem Eng 8:103533spa
dc.relation.referencesSellaoui L, Lima EC, Dotto GL, Ben LA (2017a) Adsorption of amoxicillin and paracetamol on modified activated carbons: equilibrium and positional entropy studies. J Mol Liq 234:375–381spa
dc.relation.referencesSellaoui L, Edi Soetaredjo F, Ismadji S, Cláudio Lima É, Dotto GL, Ben Lamine A, Erto A (2017b) New insights into single-compound and binary adsorption of copper and lead ions on a treated sea mango shell: experimental and theoretical studies. Phys Chem Chem Phys 19:25927–25937spa
dc.relation.referencesSellaoui L, Lima ÉC, Dotto GL, Dias SLP, Ben Lamine A (2017c) Physicochemical modeling of reactive violet 5 dye adsorption on home-made cocoa shell and commercial activated carbons using the statistical physics theory. Results Phys 7:233–237spa
dc.relation.referencesSellaoui L, Mechi N, Lima ÉC, Dotto GL, Ben Lamine A (2017d) Adsorption of diclofenac and nimesulide on activated carbon: statistical physics modeling and effect of adsorbate size. J Phys Chem Solids 109:117–123spa
dc.relation.referencesSips R (1948) Combined form of Langmuir and Freundlich equations. J Chem Phys 16:490–495spa
dc.relation.referencesSuzuki M (1990) Adsorption Engineering. Kodansha, Tokyospa
dc.relation.referencesThakur VK, Singha AS (2015) Surface modification of biopolymers. John and Wiley & Sons, inc, New Jerseyspa
dc.relation.referencesThomas HC (1944) Heterogeneous ion exchange in a flowing system. J Amer Chem Soc 66:1664–1666spa
dc.relation.referencesTóth J (2002) Adsorption Theory, Modelling and Analysis. Dekker, New Yorkspa
dc.relation.referencesUnuabonah EI, Adedapo AO, Nnamdi CO, Adewuyi A, Omorogie MO, Adebowale KO, Olu-Owolabi B, Ofomaja AE, Taubert A (2015) Successful scale-up performance of a novel papaya-clay combo adsorbent: up-flow adsorption of a basic dye. Des Water Treat 56:536–551spa
dc.relation.referencesWang C, Feng C, Gao Y, Ma X, Wu Q, Wang Z (2011) Preparation of a graphene-based magnetic nanocomposite for the removal of an organic dye from aqueous solution. Chem Eng J 173:92–97spa
dc.relation.referencesYoon YH, Nelson JH (1984) Application of gas adsorption kinetics I. A theoretical model for respirator cartridge service life. The Amer Ind Hyg Assoc J 45:509–516spa
dc.relation.referencesYuan J, Qiu F, Li P (2017) Synthesis and characterization of β-cyclodextrin-carboxymethyl cellulose-graphene oxide composite materials and its application for removal of basic fuchsin. J Iranian Chem Soc 14:1827–1837spa

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