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Crystal structure of bis{mu-(E)-2-[(2-oxidophenyl-imino)methyl]quinolin-8-olato-kappa O-4,N,N ',O '}-bis[dibutyltin(IV)]
dc.contributor.author | Camacho Camacho, Carlos | spa |
dc.contributor.author | Ortiz Pastrana, Naytzé | spa |
dc.contributor.author | garza-ortiz, ariadna | spa |
dc.contributor.author | Rojas-Oviedo, Irma | spa |
dc.date.accessioned | 2020-11-11T16:45:21Z | |
dc.date.available | 2020-11-11T16:45:21Z | |
dc.date.issued | 2017 | |
dc.identifier.issn | 2056-9890 | spa |
dc.identifier.uri | https://hdl.handle.net/11323/7259 | spa |
dc.description.abstract | Condensation of 8-hydroxyquinoline-2-carbaldehyde with 2-aminophenol gave the (E)-2-[(2-hydroxyphenylimino)methyl]quinolin-8-ol derivative that reacted with di-n-butyltin oxide with release of H2O to yield the chelate title complex, [Sn2(C4H9)4(C16H10N2O2)2]. The compound crystallizes in the triclinic space group P-1, with two independent centrosymmetric dimers in the unit cell. Each features a typical pincer-type structure where the dianionic ligand is tetradentate, coordinating to the central tin atom through both phenolate oxygen atoms, as well as through the quinoline and imine N atoms. Each metal atom adopts a distorted pentagonal–bipyramidal SnC2N2O3 coordination arising from the N,N′,O,O′-tetradentate deprotonated Schiff base, one bridging phenolate O atom of the neighbouring ligand and two butyl groups in the axial sites. | spa |
dc.format.mimetype | application/pdf | spa |
dc.language.iso | eng | |
dc.publisher | Corporación Universidad de la Costa | spa |
dc.rights | Attribution-NonCommercial-ShareAlike 4.0 International | spa |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-sa/4.0/ | spa |
dc.source | Acta Crystallogr E Crystallogr Commun | spa |
dc.subject | crystal structure | spa |
dc.subject | 8-quinolinolates | spa |
dc.subject | sevenfold coordination | spa |
dc.subject | dialkylditin(IV) compound | spa |
dc.title | Crystal structure of bis{mu-(E)-2-[(2-oxidophenyl-imino)methyl]quinolin-8-olato-kappa O-4,N,N ',O '}-bis[dibutyltin(IV)] | spa |
dc.type | Artículo de revista | spa |
dc.source.url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5209758/ | spa |
dc.rights.accessrights | info:eu-repo/semantics/openAccess | spa |
dc.identifier.doi | https://doi.org/10.1107/S2056989016018867 | spa |
dc.identifier.instname | Corporación Universidad de la Costa | spa |
dc.identifier.reponame | REDICUC - Repositorio CUC | spa |
dc.identifier.repourl | https://repositorio.cuc.edu.co/ | spa |
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dc.type.coar | http://purl.org/coar/resource_type/c_6501 | spa |
dc.type.content | Text | spa |
dc.type.driver | info:eu-repo/semantics/article | spa |
dc.type.redcol | http://purl.org/redcol/resource_type/ART | spa |
dc.type.version | info:eu-repo/semantics/acceptedVersion | spa |
dc.type.coarversion | http://purl.org/coar/version/c_ab4af688f83e57aa | spa |
dc.rights.coar | http://purl.org/coar/access_right/c_abf2 | spa |
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