Mostrar el registro sencillo del ítem

Effect on thermal oxidation in TiO2 nanostructures on nanohardness and corrosion resistance

dc.contributor.authorMuñoz Mizuno, Andreaspa
dc.contributor.authorCely Baustista, Maria Mercedesspa
dc.contributor.authorJaramillo Colpas, Javier Enriquespa
dc.contributor.authorHincapie, Duberneyspa
dc.contributor.authorCalderón Hernández, José Wilmarspa
dc.date.accessioned2021-01-12T17:04:49Z
dc.date.available2021-01-12T17:04:49Z
dc.date.issued2020
dc.identifier.issn0718-3291spa
dc.identifier.issn0718-3305spa
dc.identifier.urihttps://hdl.handle.net/11323/7677spa
dc.description.abstractThis article aimed to analyze the effect of the thermal oxidation in the corrosion resistance and the hardness properties of TiO2 nanostructures obtained by the anodizing process in the HF/H3PO4 solution. TiO2 nanostructures on Ti6Al4V obtained by anodizing processes were subjected to thermal oxidation (TO) treatments over a temperature range from 500 ºC to 620 ºC for 2 hours. Surface morphology was evaluated by using scanning electron microscopy; the hardness properties of TiO2 nanostructures were obtained by Nanoindentation measurements using a Berkovich probe with a tip radius of 150 mm. The corrosion behavior of the samples was studied using potentiodynamic polarization and electrochemical impedance spectroscopy (EIS). The results showed that TiO2 nanostructures, modified by thermal oxidation, increased the surface properties of hardness and corrosion resistance, compared to the substrate, maintaining its mixed or tubular structure. On the other hand, a transformation of nanotubes to nanopores after 600ºC was evidenced, generating significant changes in the mechanical properties of these structures.spa
dc.description.abstractEl objetivo de este artículo es analizar el efecto de oxidación térmica en la resistencia a la corrosión y las propiedades de dureza de nanoestructuras de TiO2 obtenidas por procesos de anodizado en solución de HF/ H3PO4. Las nanoestructuras de TiO2 sobre Ti6Al4V por procesos de anodizado fueron sometidas a tratamiento de oxidación térmica (OT)en un rango de 500 ºC a 620 ºC por dos (2) horas. La morfología superficial fue evaluada mediante microscopia electrónica de barrido; las propiedades de dureza de nanoestructuras de TiO2 fueron obtenidas por medidas de nanoindentación usando una probeta Berkovich de radio 150 mm. El comportamiento a la corrosión de las muestras fue estudiado usando polarización potenciodinámica y espectroscopia de impedancia electroquímica (EIS). Los resultados mostraron que la nanoestructuras de TiO2, modificadas por oxidación térmica, incrementaron las propiedades superficiales de dureza y resistencia a la corrosión, comparadas a las del substrato, manteniendo su estructura mixta o tubular. Además, se evidenció una transformación de nanotubos a nanoporos después de 600 ºC generando cambios significativos en las propiedades mecánicas de estas estructuras.spa
dc.format.mimetypeapplication/pdfspa
dc.language.isoeng
dc.publisherCorporación Universidad de la Costaspa
dc.rightsCC0 1.0 Universalspa
dc.rights.urihttp://creativecommons.org/publicdomain/zero/1.0/spa
dc.sourceIngeniarespa
dc.subjectNanostructuresspa
dc.subjectTiO2spa
dc.subjectNanohardnessspa
dc.subjectEISspa
dc.subjectThermal oxidationspa
dc.subjectNanostructurasspa
dc.subjectNanodurezaspa
dc.subjectOxidación térmicaspa
dc.titleEffect on thermal oxidation in TiO2 nanostructures on nanohardness and corrosion resistancespa
dc.typeArtículo de revistaspa
dc.source.urlhttps://scielo.conicyt.cl/scielo.php?script=sci_abstract&pid=S0718-33052020000300362&lng=es&nrm=iso&tlng=enspa
dc.rights.accessrightsinfo:eu-repo/semantics/openAccessspa
dc.identifier.doihttp://dx.doi.org/10.4067/S0718-33052020000300362.spa
dc.identifier.instnameCorporación Universidad de la Costaspa
dc.identifier.reponameREDICUC - Repositorio CUCspa
dc.identifier.repourlhttps://repositorio.cuc.edu.co/spa
dc.relation.references[1] M. Geetha, A.K. Singh, R. Asokamani and A.K. Gogia. “Ti based biomaterials, the ultimate choice for orthopaedic implants - A review”. Prog. Mater. Sci. Vol. 54, Issue 3, pp. 397-425. May, 2009.spa
dc.relation.references[2] M. Long and H.J. Rack. “Titanium alloys in total joint replacement--a materials science perspective”. Biomaterials. Vol. 19, Issue 18, pp. 1621-1639. Sep., 1998.spa
dc.relation.references[3] A. Bandyopadhyay, F. Espana, V.K. Balla, S. Bose, Y. Ohgami and N.M. Davies. “Influence of porosity on mechanical properties and in vivo response of Ti6Al4V implants”. Acta Biomater. Vol. 6, Issue 4, pp. 1640-1648. Apr., 2010.spa
dc.relation.references[4] S. Bose and A. Bandyopadhyay. “Introduction to Biomaterials”. Characterization of Biomaterials, pp. 1-9. 2013.spa
dc.relation.references[5] S.R. Paital and N.B. Dahotre. “Calcium phosphate coatings for bio-implant applications: Materials, performance factors, and methodologies”. Mater. Sci. Eng. R Reports. Vol. 66, Issue 1-3, pp. 1-70. Aug., 2009.spa
dc.relation.references[6] S.D. Sartale, A.A. Ansari and S.-J. Rezvani. “Influence of Ti film thickness and oxidation temperature on TiO2 thin film formation via thermal oxidation of sputtered Ti film”. Mater. Sci. Semicond. Process. Vol. 16, Issue 6, pp. 2005-2012. Dec., 2013.spa
dc.relation.references[7] M. Fazel, H.R. Salimijazi, M.A. Golozar and M.R. Garsivaz. “Applied Surface Science A comparison of corrosion, tribocorrosion and electrochemical impedance properties of pure Ti and Ti6Al4V alloy treated by micro-arc oxidation process”. Appl. Surf. Sci. Vol. 324, pp. 751-756. 2015.spa
dc.relation.references[8] Q. Chen and G.A. Thouas. “Metallic implant biomaterials”. Mater. Sci. Eng. R Reports. Vol. 87, pp. 1-57. 2015.spa
dc.relation.references[9] S. Kumar, T.S.N.S. Narayanan, S.G.S. Raman and S.K. Seshadri. “Thermal oxidation of CP-Ti: Evaluation of characteristics and corrosion resistance as a function of treatment time”. Mater. Sci. Eng. C. Vol. 29, Issue 6, pp. 1942-1949. Aug., 2009.spa
dc.relation.references[10] S. Kumar, T.S.N. Sankara Narayanan, S.G.S. Raman and S.K. Seshadri. “Thermal oxidation of Ti6Al4V alloy: Microstructural and electrochemical characterization”. Mater. Chem. Phys. Vol. 119, Issue 1-2, pp. 337- 346. Jan., 2010.spa
dc.relation.references[11] S. Wang, Z. Liao, Y. Liu and W. Liu. “Influence of thermal oxidation duration on the microstructure and fretting wear behavior of Ti6Al4V alloy”. Surf. Coatings Technol. Vol. 240, pp. 470-477. 2014.spa
dc.relation.references[12] R. Narayanan and S.K. Seshadri. “Phosphoric acid anodization of Ti-6Al-4V - Structural and corrosion aspects”. Corros. Sci. Vol. 49, Issue 2, pp. 542-558. Feb., 2007.spa
dc.relation.references[13] P. Roy, S. Berger and P. Schmuki. “TiO2 nanotubes: Synthesis and applications”.Angew. Chemie - Int. Ed. Vol. 50, Issue 13, pp. 2904-2939. 2011.spa
dc.relation.references[14] E. Matykina, A. Conde, J. De Damborenea, D.M.Y. Marero and M.A. Arenas. “Growth of TiO2-based nanotubes on Ti-6Al-4V alloy”. Electrochim. Acta. Vol. 56, Issue 25, pp. 9209-9218. 2011.spa
dc.relation.references[15] V. Vega. “Fabricación y Caracterización de Materiales Nanoestructurados Obtenidos Mediante Técnicas Electroquímicas”. Univ. Oviedo. 2012.spa
dc.relation.references[16] J.M. Hernández-López, A. Conde, J.J. De Damborenea and M.A. Arenas. “TiO2 nanotubes with tunable morphologies”. RSC Adv. Vol. 4, Issue 107, pp. 62576-62585. 2014.spa
dc.relation.references[17] M. Kulkarni, A. Mazare, E. Gongadze, S. Perutkova, V. Kralj-Iglic, I. Milosev, P. chmuki, A. Iglic and M. Mozetic. “Titanium nanostructures for biomedical applications”. Nanotechnology. Vol. 26, pp. 62002 (1-18). 2015.spa
dc.relation.references[18] S. Minagar, C.C. Berndt, J. Wang, E. Ivanova and C. Wen. “A review of the application of anodization for the fabrication of nanotubes on metal implant surfaces”. Acta Biomater. Vol. 8, Issue 8, pp. 2875-2888. 2012.spa
dc.relation.references[19] J.A. Fernandes, E.C. Kohlrausch, S. Khan and R.C. Brito. “E ff ect of anodisation time and thermal treatment temperature on the structural and photoelectrochemical properties of TiO2 nanotubes”. J. Solid State Chem. Vol. 251, pp. 217-223. February, 2017.spa
dc.relation.references[20] E. Matykina, J.M. Hernandez-lópez, A. Conde, C. Domingo, J.J. De Damborenea and M.A. Arenas. “Electrochimica Acta Morphologies of nanostructured TiO2 doped with F on Ti6Al-4V alloy”. Vol. 56, pp. 2221-2229. 2011.spa
dc.relation.references[21] B. Munirathinam and L. Neelakantan. “Role of crystallinity on the nanomechanical and electrochemical properties of TiO2 nanotubes”. J. Electroanal. Chem. Vol. 770, pp. 73-83. 2016.spa
dc.relation.references[22] T. Dikici and M. Toparli. “Microstructure and mechanical properties of nanostructured and microstructured TiO2 films”. Mater. Sci. Eng. A. Vol. 661, pp. 19-24. 2016.spa
dc.relation.references[23] R. Narayanan, P. Mukherjee and S.K. Seshadri. “Synthesis, corrosion and wear of anodic oxide coatings on Ti-6Al-4V”. J. Mater. Sci. Mater. Med. Vol. 18, Issue 5, pp. 779-786. 2007.spa
dc.relation.references[24] H. Song, M. Kim, G. Jung, M. Vang and Y. Park. “The effects of spark anodizing treatment of pure titanium metals and titanium alloys on corrosion characteristics”. Surf. Coatings Technol. Vol. 201, Issue 21, pp. 8738-8745. Aug., 2007.spa
dc.relation.references[25] M. de las M. Cely Bautista. “Efecto de la modificacion supercicial de la aleación Ti6Al4V en condición de contacto lubricado con polietileno de ultra alto peso molecular (UHMWPE)”. Universidad Nacional de Colombia. 2013.spa
dc.relation.references[26] S. Kumar, T.S.N.S. Narayanan, S.G.S. Raman and S.K. Seshadri. “Surface modification of CP-Ti to improve the fretting-corrosion resistance: Thermal oxidation vs. anodizing”. Mater. Sci. Eng. C. Vol. 30, Issue 6, pp. 921- 927. Jul., 2010.spa
dc.relation.references[27] Y. Rambabu, M. Jaiswal and S.C. Roy. “Effect of annealing temperature on the phase transition, structural stability and photo-electrochemical performance of TiO2 multi-leg nanotubes”. Vol. 278, pp. 255-261. 2016.spa
dc.relation.references[28] S. Wang, Z. Liao, Y. Liu and W. Liu. “Influence of thermal oxidation temperature on the microstructural and tribological behavior of Ti6Al4V alloy”. Surf. Coatings Technol. Vol. 240, pp. 470-477. Feb., 2014.spa
dc.relation.references[29] B. Munirathinam and L. Neelakantan. “Titania nanotubes from weak organic acid electrolyte : Fabrication, characterization and oxide fi lm properties”. Mater. Sci. Eng. C. Vol. 49, pp. 567-578. 2015.spa
dc.relation.references[30] W.-Q. Yu, J. Qiu, L. Xu and F.-Q. Zhang. “Corrosion behaviors of TiO2 nanotube layers on titanium in Hank’s solution”. Biomed. Mater. Vol. 4, Issue 6, p. 065012. 2009.spa
dc.relation.references[31] M. Sarraf, E. Zalnezhad, A.R. Bushroa, A.M.S. Hamouda, A.R. Rafieerad and B. Nasiri-Tabrizi. “Effect of microstructural evolution on wettability and tribological behavior of TiO2 nanotubular arrays coated on Ti-6Al-4V”. Ceram. Int. Vol. 41, Issue 6, pp. 7952-7962. 2015.spa
dc.relation.references[32] K.M. Deen, A. Farooq, M.A. Raza and W. Haider. “Effect of electrolyte composition on TiO2 nanotubular structure formation and its electrochemical evaluation”. Electrochim. Acta. Vol. 117, pp. 329-335. 2014.spa
dc.relation.references[33] J. Huang, X. Zhang, W. Yan, Z. Chen, X. Shuai, A. Wang and Y. Wang. “Nanotubular topography enhances the bioactivity of titanium implants”. Nanomedicine, pp. 1-11. 2017.spa
dc.relation.references[34] K. Das, S. Bose and A. Bandyopadhyay. “TiO2 nanotubes on Ti: Influence of nanoscale morphology on bone cell-materials interaction”. J. Biomed. Mater. Res. - Part A. Vol. 90, Issue 1, pp. 225-237. 2009.spa
dc.relation.references[35] G.A. Crawford, N. Chawla, K. Das, S. Bose and A. Bandyopadhyay. “Microstructure and deformation behavior of biocompatible TiO2 nanotubes on titanium substrate”. Acta Biomater. Vol. 3, Issue 3, pp. 359-367. 2007.spa
dc.relation.references[36] A. Munoz-Mizuno, A. Sandoval-Amador, M.M. Cely, D.Y. Pena-Ballesteros and R.J. Hernandez. “TiO2 Nanostructures: Voltage Influence in Corrosion Resistance and Human Osteosarcoma HOS Cell Responses”. Indian J. Sci. Technol. Vol. 11, Issue 22, pp. 1-9. 2018.spa
dc.relation.references[37] M. Sarraf, E. Zalnezhad, A.R. Bushroa and A.M.S. Hamouda. “Effect of microstructural evolution on wettability and tribological behavior of TiO2 nanotubular arrays coated on Ti - 6Al - 4V”. Vol. 41, pp. 7952-7962. 2015.spa
dc.relation.references[38] L.H. Bessauer. “Desenvolvimento e Caracterização de Nanotubos de TiO2 em Implantes de Titânio”. Pontifícia Universida de Católica do Rio Grande do Sul. 2011.spa
dc.relation.references[39] L. Mohan, C. Anandan and N. Rajendran. “Electrochemical behaviour and bioactivity of self-organized TiO2 nanotube arrays on Ti-6Al-4V in Hanks’ solution for biomedical applications”. Electrochim. Acta. Vol. 155, pp. 411-420. 2015.spa
dc.relation.references[40] S. Bauer, J. Park, K. von der Mark and P. Schmuki. “Improved attachment of mesenchymal stem cells on super-hydrophobic TiO2 nanotubes”. Acta Biomater. Vol. 4, Issue 5, pp. 1576-1582. 2008.spa
dc.relation.references[41] A. Biswas, I. Manna, U.K. Chatterjee, U. Bhattacharyya and D.J. Majumdar. “Evaluation of electrochemical properties of thermally oxidised Ti-6Al-4V for bioimplant application”. Surf. Eng. Vol. 25, Issue 2, pp. 141-145. Feb., 2009.spa
dc.relation.references[42] L. Le Guéhennec, A. Soueidan, P. Layrolle and Y. Amouriq. “Surface treatments of titanium dental implants for rapid osseointegration”. Dent. Mater. Vol. 23, Issue 7, pp. 844-854. Jul., 2007.spa
dc.relation.references[43] E.S. Gadelmawla, M.M. Koura, T.M.A. Maksoud, I.M. Elewa and H.H. Soliman. “Roughness parameters”. J. Mater. Process. Technol. Vol. 123, Issue 1, pp. 133-145. 2002.spa
dc.relation.references[44] B. Munirathinam and L. Neelakantan. “Role of crystallinity on the nanomechanical and electrochemical properties of TiO2 nanotubes”. J. Electroanal. Chem. Vol. 770, pp. 73-83. 2016.spa
dc.relation.references[45] Q. Chen, G.D. McEwen, N. Zaveri, R. Karpagavalli and A. Zhou. “Corrosion Resistance of Ti6Al4V with Nanostructured TiO2 Coatings”. First Edit. Elsevier Inc. 2012.spa
dc.relation.references[46] J. Caballero Sarmiento, E. Correa Muñoz and H. Estupiñan Duran. “Analysis of the biocompatibility of Ti6Al4V and stainless steel 316 LVM based on pH effects, applying criteria of the ASTM F2129 standard”. Ingeniare. Revista Chilena de Ingeniería. Vol. 25 Nº 1, pp. 95-105. 2017.spa
dc.relation.references[47] Y. Liu, S. Kim, J.A. McLeod, J. Li, X. Guo, T.-K. Sham and L. Liu. “The effect of crystal structure of TiO2 nanotubes on the formation of calcium phosphate coatings during biomimetic deposition”. Appl. Surf. Sci. Vol. 396, pp. 1212-1219. 2017.spa
dc.relation.references[48] J. Chen, Z. Zhang, J. Ouyang, X. Chen, Z. Xu and X. Sun. “Bioactivity and osteogenic cell response of TiO2 nanotubes coupled with nanoscale calcium phosphate via ultrasonification-assisted electrochemical deposition”. Appl. Surf. Sci. Vol. 305, pp. 24-32. 2014.spa
dc.relation.references[49] O. Pinilla and A. Siado. “Caracterizacion Microestructural de la Aleacion de Titanio Ti6Al4V Oxidada Térmicamente”. Universidad Autónoma del Caribe. 2014.spa
dc.relation.references[50] A. Sandoval-Amador, N.D. Montañez Supelano, A.M. Vera Arias, P. Escobar Rivero and D.Y. Peña-Ballesteros. “HOS cell adhesion on TiO2 nanotubes texturized by laser engraving”. J. Phys. Conf. Ser. Vol. 786, pp. 1-6. 2017.spa
dc.relation.references[51] A. Sandoval-Amador, L.J. MirandaVesga, J. Pérez and D.Y. Peña-Ballesteros. “Biofuncionalización de Ti6Al4V mediante crecimiento de nanoestructuras de TiO2 con contenido de calcio y fósforo”. Materia. Vol. 21, Issue 3, pp. 606-614. 2016.spa
dc.title.translatedEfecto de la oxidación térmica en nanoestructuras de TiO2 sobre la nanodureza y resistencia a la corrosiónspa
dc.type.coarhttp://purl.org/coar/resource_type/c_6501spa
dc.type.contentTextspa
dc.type.driverinfo:eu-repo/semantics/articlespa
dc.type.redcolhttp://purl.org/redcol/resource_type/ARTspa
dc.type.versioninfo:eu-repo/semantics/acceptedVersionspa
dc.type.coarversionhttp://purl.org/coar/version/c_ab4af688f83e57aaspa
dc.rights.coarhttp://purl.org/coar/access_right/c_abf2spa


Ficheros en el ítem

Thumbnail
Nombre:
license_rdf
Tamaño:
701bytes
Formato:
application/rdf+xml
Ver/
Thumbnail
Nombre:
Effect on thermal oxidation in ...
Tamaño:
2.010Mb
Formato:
PDF
Ver/

Este ítem aparece en la(s) siguiente(s) colección(ones)

  • Artículos científicos [3154]
    Artículos de investigación publicados por miembros de la comunidad universitaria.

Mostrar el registro sencillo del ítem

CC0 1.0 Universal
Excepto si se señala otra cosa, la licencia del ítem se describe como CC0 1.0 Universal