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Optimization of ketoprofen adsorption from aqueous solutions and simulated effluents using H2SO4 activated Campomanesia guazumifolia bark

dc.contributor.authorPreigschadt, Isadora A.spa
dc.contributor.authorBevilacqua, Raíssa C.spa
dc.contributor.authorNetto, Matias S.spa
dc.contributor.authorgeorgin, jordanaspa
dc.contributor.authorFranco, Dison S. P.spa
dc.contributor.authorMallmann, Evandro S.spa
dc.contributor.authorPinto, Dianaspa
dc.contributor.authorFoletto, Edsonspa
dc.contributor.authorDotto, Guilherme Luizspa
dc.date.accessioned2022-04-29T13:03:45Z
dc.date.available2023
dc.date.available2022-04-29T13:03:45Z
dc.date.issued2021
dc.identifier.citationPreigschadt, .A., Bevilacqua, R.C., Netto, M.S. et al. Optimization of ketoprofen adsorption from aqueous solutions and simulated effluents using H2SO4 activated Campomanesia guazumifolia bark. Environ Sci Pollut Res 29, 2122–2135 (2022). https://doi.org/10.1007/s11356-021-15668-7spa
dc.identifier.issn0944-1344spa
dc.identifier.urihttps://hdl.handle.net/11323/9137spa
dc.description.abstractThis study used the bark of the forest species Campomanesia guazumifolia modified with H2SO4 to absorb the anti-inflammatory ketoprofen from aqueous solutions. FTIR spectra confirmed that the main bands remained after the chemical treatment, with the appearance of two new bands related to the elongation of the carbonyl group present in hemicellulose. Micrographs confirmed that the surface started to contain a new textural shape after acid activation, having new pores and cavities. The drug adsorption’s optimum conditions were obtained by response surface methodology (RSM). The adsorption was favored at acidic pH (2). The dosage of 1 g L−1 was considered ideal, obtaining good indications of removal and capacity. The Elovich model very well represented the kinetic curves. The isotherm studies indicated that the increase in temperature negatively affected the adsorption of ketoprofen. A maximum adsorption capacity of 158.3 mg g−1 was obtained at the lower temperature of 298 K. Langmuir was the best-fit isotherm. Thermodynamic parameters confirmed the exothermic nature of the system (ΔH0 = −8.78 kJ mol−1). In treating a simulated effluent containing different drugs and salts, the removal values were 35, 50, and 80% at 15, 30, and 180 min, respectively. Therefore, the development of adsorbent from the bark of Campomanesia guazumifolia treated with H2SO4 represents a remarkable alternative for use in effluent treatment containing ketoprofen.eng
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dc.language.isoeng
dc.publisherSpringer Science + Business Mediaspa
dc.rights© 2022 Springer Nature Switzerland AG. Part of Springer Nature.spa
dc.rightsAtribución-NoComercial-CompartirIgual 4.0 Internacional (CC BY-NC-SA 4.0)spa
dc.rights.urihttps://creativecommons.org/licenses/by-nc-sa/4.0/spa
dc.titleOptimization of ketoprofen adsorption from aqueous solutions and simulated effluents using H2SO4 activated Campomanesia guazumifolia barkeng
dc.typeArtículo de revistaspa
dc.identifier.urlhttps://doi.org/10.1007/s11356-021-15668-7spa
dc.source.urlhttps://link.springer.com/article/10.1007/s11356-021-15668-7spa
dc.rights.accessrightsinfo:eu-repo/semantics/embargoedAccessspa
dc.identifier.doi10.1007/s11356-021-15668-7spa
dc.identifier.eissn1614-7499spa
dc.identifier.instnameCorporación Universidad de la Costaspa
dc.identifier.reponameREDICUC - Repositorio CUCspa
dc.identifier.repourlhttps://repositorio.cuc.edu.co/spa
dc.publisher.placeGermanyspa
dc.relation.ispartofjournalEnvironmental Science and Pollution Researchspa
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dc.subject.proposalCampomanesia guazumifoliaeng
dc.subject.proposalAcid treatmenteng
dc.subject.proposalAdsorptioneng
dc.subject.proposalBarkeng
dc.subject.proposalKetoprofeneng
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dc.relation.citationvolume29spa
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