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Investigation of biochar from Cedrella fissilis applied to the adsorption of atrazine herbicide from an aqueous medium

dc.contributor.authorHernandes, Paola T.spa
dc.contributor.authorDison S.P., Francospa
dc.contributor.authorgeorgin, jordanaspa
dc.contributor.authorP. G. Salau, Ninaspa
dc.contributor.authorDotto, Guilherme Luizspa
dc.date.accessioned2022-05-23T12:55:14Z
dc.date.available2024
dc.date.available2022-05-23T12:55:14Z
dc.date.issued2022
dc.identifier.issn2213-3437spa
dc.identifier.urihttps://hdl.handle.net/11323/9184spa
dc.description.abstractBiochar was produced from the sawdust of the wood forest species Cedrella fissilis and later used as an adsorbent to remove atrazine herbicide from aqueous media. Biochar showed high thermal stability, an amorphous structure, and a highly irregular surface, mainly composed of carbon-containing bonds. The isothermal curves confirmed that the increase in temperature favored the adsorption of the herbicide. The Langmuir model best suited the experimental equilibrium data, with the maximum adsorption capacity of 7.68 mg g-1 at 328 K. The thermodynamic parameters confirmed a spontaneous process of an endothermic nature governed by physical interactions (interactions of van der Waals and hydrogen bonds). Kinetic studies showed that equilibrium was reached within 180 min. The linear driving force model (LDF) showed good statistical adjustment to the experimental data, where it was observed that the diffusion coefficient increased with the concentration of adsorbate. Biochar can be reused in up to three cycles. Finally, the adsorbent showed good efficiency in real water samples from rivers contaminated with atrazine, with 76.58% and 71.29% removal.eng
dc.format.extent10 páginasspa
dc.format.mimetypeapplication/pdfspa
dc.language.isoeng
dc.publisherElsevier BVspa
dc.rightsAtribución-NoComercial-SinDerivadas 4.0 Internacional (CC BY-NC-ND 4.0)spa
dc.rights© 2022 Elsevier Ltd. All rights reserved.spa
dc.rights.urihttps://creativecommons.org/licenses/by-nc-nd/4.0/spa
dc.titleInvestigation of biochar from Cedrella fissilis applied to the adsorption of atrazine herbicide from an aqueous mediumeng
dc.typeArtículo de revistaspa
dc.identifier.urlhttps://doi.org/10.1016/j.jece.2022.107408spa
dc.source.urlhttps://www.sciencedirect.com/science/article/pii/S2213343722002810spa
dc.rights.accessrightsinfo:eu-repo/semantics/embargoedAccessspa
dc.identifier.doi10.1016/j.jece.2022.107408spa
dc.identifier.instnameCorporación Universidad de la Costaspa
dc.identifier.reponameREDICUC - Repositorio CUCspa
dc.identifier.repourlhttps://repositorio.cuc.edu.co/spa
dc.publisher.placeUnited Kingdomspa
dc.relation.ispartofjournalJournal of Environmental Chemical Engineeringspa
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dc.subject.proposalAdsorptioneng
dc.subject.proposalAtrazineeng
dc.subject.proposalBiochareng
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dc.subject.proposalRiver watereng
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